Use of potassium-form cation-exchange resin as a conductimetric enhancer in ion-exclusion chromatography of aliphatic carboxylic acids

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Use of potassium-form cation-exchange resin as a conductimetric enhancer in ion-exclusion chromatography of aliphatic carboxylic acids.

In this study, a cation-exchange resin (CEX) of the K(+)-form, i.e., an enhancer resin, is used as a postcolumn conductimetric enhancer in the ion-exclusion chromatography of aliphatic carboxylic acids. The enhancer resin is filled in the switching valve of an ion chromatograph; this valve is usually used as a suppressor valve in ion-exchange chromatography. An aliphatic carboxylic acid (e.g., ...

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Modeling of Ion-exclusion and Vacancy Ion-exclusion Chromatography on a Strongly Acidic Cation-exchange Resin in the H+ Form

Ion-exclusion chromatography (IEC) can sometimes be used for separation of the weak acids using pure water as mobile phase. Characteristic leading (i.e. frontally tailing) peaks are obtained and retention depends on the concentration of solutes. It was recently shown that this order could be reversed. In vacant ion exclusion chromatography (vIEC) sample flows as mobile phase and pure water is i...

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Use of a polystyrene-divinylbenzene-based weakly acidic cation-exchange resin column and propionic acid as an eluent in ion-exclusion/adsorption chromatography of aliphatic carboxylic acids and ethanol in food samples.

We developed an ion-exclusion/adsorption chromatography (IEAC) method employing a polystyrene-divinylbenzene-based weakly acidic cation-exchange resin (PS-WCX) column with propionic acid as the eluent for the simultaneous determination of multivalent aliphatic carboxylic acids and ethanol in food samples. The PS-WCX column well resolved mono-, di-, and trivalent carboxylic acids in the acidic e...

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Ion-exclusion/cation-exchange chromatography (IEC/CEC) on a weakly acidic cation-exchange resin using on acidic eluent,

Ion-exclusion/cation-exchange chromatography (IEC/CEC) on a weakly acidic cation-exchange resin using on acidic eluent, developed by Tanaka et al. in 1994, has been employed to monitor the quality of environmental water samples such as acid rainwater and river water, to analyze body fluid samples such as saliva, and to evaluate water purification by photocatalytic materials.1–8 One advantage of...

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Carboxylic cation exchange resin effects in dogs.

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ژورنال

عنوان ژورنال: Talanta

سال: 2009

ISSN: 0039-9140

DOI: 10.1016/j.talanta.2009.03.042